Phosphorus, one of the most abundant elements in the Earth (∼0.1%), has attracted much attention in the last five years since the rediscovery of two-dimensional (2D) black phosphorus (BP) in 2014. The successful scaling down of BP endows this ''old material'' with new vitality, resulting from the intriguing se
The successful isolation of phosphorene (atomic layer thick black phosphorus) in 2014 has currently aroused the interest of 2D material researchers. In this review, first, the fundamentals of phosphorus allotropes, phosphorene, and black phosphorus, are briefly introduced, along with their structures, properties, and synthesis methods. Second, the …
This review specifically highlights the very recent progress in the synthesis and applications of black phosphorus in the energy process, including secondary …
The latest recent advances of BP-based functional materials in energy storage applications including lithium-, magnesium- and sodium-ion batteries, …
Black phosphorus (BP) has unmatched application advantages as a two-dimensional semiconductor in electronic and optoelectronic devices owing to its tunable direct bandgap, high carrier mobility, and significant in-plane anisotropy. However, the commercial use of BP is limited owing to its instability. BP oxidizes easily under ambient …
Two-dimensional (2D) black phosphorus (BP) has attracted great attention in recent years in fundamental research as well as optoelectronics applications. The controllable synthesis of high-quality BP is vital to the investigation of its intrinsic physical properties and versatile applications. Originally, BP was mostly synthesized …
Thirdly, the applications of BP in energy storage are introduced, especially the application of BP-based materials in lithium-ion batteries. Finally, based on preparation, surface functionalization, and lithium-ion battery of 2D BP, the current research status and possible future development direction are put forward.
This unique structure gives rise to tunable chemical and physical features suitable for electrochemical energy conversion and storage applications [11], [12]. Since Novoselov and Geim [13] synthesized 2D graphene from graphite by Scotch tape method in 2004, there has been a wave of interest in this area [14], [15] .
However, the systematic summarization of black phosphorus in energy storage materials, especially in potassium-ion batteries (PIBs), LABs, supercapacitors, …
This review focuses on the structure and properties of two-dimensional black phosphorus (BP). First, the crystal and electronic structures of BP are introduced. Second, the anisotropy properties of BP including the band structure and mechanical, thermal, electric, thermoelectric, optical, optoelectronic, magnetic, and magneto-optic …
Black phosphorus with a long history of ∼100 years has recently attracted extraordinary attention and has become a promising candidate for energy storage and conversion owing to its unique layered structure, impressive carrier mobility, remarkable in-plane anisotropic properties, and tunable bandgap from 0.3
Herein, we present the first review of recent progress in BP-based electrochemical energy storage device. The preparation and electrochemical properties of black phosphorus, recent advances, …
In this review, the unique properties of Black Phosphorus are first discussed and compared with other well explored 2D materials (Graphene, WSe 2, MoS 2 and h-BN). Also various synthesis methods of BP NPs are briefly summarized. Its various biomedical applications and toxicity concerns are subsequently reviewed. 2.
Being chemically and electronically active, phosphorene shows vast potential for photodetectors,[54–57] field-effect transistors (FETs),[58–62] rechargeable batteries,[63,64] thermoelectric ...
BPNSs are a 2D–form of BP, and many methods have been used to prepare BPNSs, almost all of which were made from bulk BP. BPNSs exhibit properties of both phosphorus and 2D–materials, and the study of BP will be beneficial to the study of BPNSs. This review drew lessons from analyzing the results obtained using VOSviewer.
Energy Storage Devices In article number 2000148, Amin Rabiei Baboukani, Chunlei Wang, and co‐workers summarize the fundamentals and latest advances in liquid‐based exfoliation of black ...
As a thermodynamically stable semiconductor material, black phosphorus (BP) has potential application in the field of energy storage and conversion. The preparation of black phosphorus is still limited to the laboratory, which is far from adequate to meet the requirements of future industrial applications. Here, the gram-scale black …
Recent advances on black phosphorus for energy storage, catalysis, and sensor applications Adv. Mater., 30 (2018), p. 1800295 ... Growth mechanism of black phosphorus synthesized by different ball milling techniques J. Alloys Compd., 784 …
Phosphorene, the single- or few-layer form of black phosphorus, was recently rediscovered as a two-dimensional layered material holding great promise for applications in electronics and optoelectronics. Research into its fundamental properties and device applications has since seen exponential growth. In this Perspective, we …
a thermodynamically stable semiconductor material, black phosphorus (BP) has potential application in field of energy storage ... Insight into the growth mechanism of black phosphorus Article Full ...
This review specifically highlights the very recent progress in the synthesis and applications of black phosphorus in the energy process, including secondary battery system, supercapacitor device, and catalysis reaction.
In this review, the significant advances recently made for the mechanism and application of BP in solar cells, Li /Ka-/Mg-/Na-ion and Li S batteries, …
A. Rabiei Baboukani, I. Khakpour, V. Drozd and C. Wang, Liquid-Based Exfoliation of Black Phosphorus into Phosphorene and Its Application for Energy Storage Devices, Small Struct., 2021, 2 (5), 2000148 CrossRef CAS.
In the last few years, new two-dimensional (2-D) materials have garnered the scientific community''s attention with the growing demand for functionalized materials for advanced electrical and biomedical applications. Among all the developed 2-D materials, black phosphorus and FLBP (few-layer black phosphorus)
phorus) in 2014 has currently aroused the interest of 2D material researchers. In this review, first, the fundamentals of phosphorus allotropes, phos-. phorene, and black phosphorus, are briefly ...
Graphical abstract. Scalable production of black phosphorus flakes and quantum dots by liquid-phase exfoliation realizes their diverse applications including super capacitor, battery, transistor, sensor, optical devices, memory device, photocatalyst, solar cell, bioimaging and so on.
The mechanism and application of BP in Li-/Na-ion battery anodes, oxygen evolution reaction/hydrogen evolution reaction catalysis, photocatalytic hydrogen production, and …
Black phosphorus possesses advantages such as tunable band gap, high carrier mobility, strong light-matter interactions, and high lithium storage capacity, making it a promising …
Black phosphorus (BP) is a 2D in-plane anisotropic material with an excellent carrier mobility and a narrow direct bandgap [25][26][27][28]. Formed by layered sp 3 -hybridized phosphorus atoms, BP ...
Following graphene, MXenes, and transition metal dichalcogenides (TMDs), black phosphorus (BP) has recently been introduced as a new member of the 2D materials family. Recently, the intensified research in BP has been motivated not only by its appealing properties, such as tunable band gap and high carrier mobility, but also by the strong …
Two-dimensional black phosphorus (2D BP), well known as phosphorene, has triggered tremendous attention since the first discovery in 2014. The unique puckered monolayer structure endows 2D BP intriguing properties, which facilitate its potential applications in various fields, such as catalyst, energy storage, sensor, etc. Owing to …