The photovoltaic-thermochemical (PVTC) hybrid system is an emerging technology for improving the efficiencies and dispatchability of solar power via complementation between concentrated solar PV and solar thermochemical conversions. In order to improve the PV efficiency and decrease the heat losses of the reactor, the concentration ratio is usually …
The methanol conversion of the novel reactor is experimentally assessed, which is 12.1 percentage points (relative improvement of 26.5%) higher than that of conventional reactors with serpentine flow channels design. ... The efficient solar energy power generation of the PVTC system with energy storage ratio ensures considerable …
1. Introduction. Methanol is a promising liquid energy carrier [1] due to its relatively high volumetric and gravimetric energy density and simple handling, but it has a significantly lower roundtrip efficiency when compared with other energy storage technologies, e.g., batteries [2].Nevertheless, even when it is not converted back to …
Figure 1. Schematic of methanol storage with carbon cycling. The Allam turbine combusts methanol in pure oxygen and returns the carbon dioxide to join the electrolytic hydrogen for synthesis to methanol. Methanol is stored as a liquid at ambient temperature and pressure, oxygen is stored as a liquid at - 183 ∘ C, and carbon dioxide is …
Composites composed of a polymer matrix and inorganic fillers have attracted tremendous attention owing to their promising application in flexible dielectric film capacitors. However, boosting the energy density while ensuring a high charging-discharging efficiency is still a huge challenge. In this work, Ba0.6Sr0.4TiO3 nanofibers …
Conventional MSR reactors are challenged by undesirable performances in heat transfer and methanol conversion, impacting the performances of power generation and energy storage of PVTC systems. In this work, an innovative fractal tree-shaped structure is introduced into the flow channels configuration of an MSR reactor to enhance …
The optimized energy storage density of 12.32 J/cm 3 and an efficiency of 64.87% are obtained in the SiO 2-2h/PVTC/BZT-1h/PVTC/SiO 2-2h multilayer composite films. The INL forms an interfacial barrier layer at the electrode–dielectric interface, while the development of breakdown path can be inhibited at the dielectric–dielectric interface ...
DOI: 10.1021/ACSAEM.1C00535 Corpus ID: 237737169; Ultra-Fine Gold Nanoparticles Enabled Au-BST NF/PVTC Composites to Have Excellent Energy Storage Performance @article{Xiong2021UltraFineGN, title={Ultra-Fine Gold Nanoparticles Enabled Au-BST NF/PVTC Composites to Have Excellent Energy Storage Performance}, …
The thermal energy is further utilized to drive endothermic reaction (i.e., methanol decomposition) and upgraded to chemical energy in syngas. Owing to full-spectrum utilization of solar energy and upgrade from thermal energy to chemical energy, net solar-to-electricity efficiency of 41% [25] and stable power supply around the clock …
Energy storage materials play a critical role in energy harvesting devices, as their performance greatly impacts energy harvesting efficiency [15], [16], [17].Energy storage materials are functional materials that utilize physical or chemical changes in substances to store energy [18], [19], [20].The ideal energy storage material …
Conventional MSR reactors are challenged by undesirable performances in heat transfer and methanol conversion, impacting the performances of power generation and energy storage of PVTC systems. In this work, an innovative fractal tree-shaped structure is introduced into the flow channels configuration of an MSR reactor to enhance …
The high operating temperature of the PV part, i.e. a photon enhanced thermionic emission (PETE) module, makes it possible for primary fossil fuel (i.e. methane) to be integrated …
Conventional MSR reactors are challenged by undesirable performances in heat transfer and methanol conversion, impacting the performances of power generation …
energy storage capability, and round-the-clock service capabilities [13], among which ... [14]. For example, our previous studies showed that a methanol-based PVTC system could reach a theoretical net solar-to-electric efficiency of 43% [5], after ...
Methanol is a leading candidate for storage of solar-energy-derived renewable electricity as energy-dense liquid fuel, yet there are different approaches to …
Request PDF | On Jul 1, 2021, Xiaoying Xiong and others published Ultra-Fine Gold Nanoparticles Enabled Au-BST NF/PVTC Composites to Have Excellent Energy Storage ...
The photovoltaic/thermochemical (PVTC) hybrid system converts thermal energy dissipated by concentrating photovoltaic cells to gain in power generation via the …
Energy storage for multiple days can help wind and solar supply reliable power. Synthesizing methanol from carbon dioxide and electrolytic hydrogen provides such ultra-long-duration storage in liquid form. Carbon dioxide can be captured from Allam cycle turbines burning methanol and cycled back into methanol synthesis. Methanol storage …
The optimal net solar-electric efficiency of the PVTC system with the six-chamber reactor can reach 42.2% at 250 °C and 1.75 ml min −1 methanol solution flow rate, which is 3.5 percentage points higher than that of the …
Polymer-based flexible dielectrics have been widely used in capacitor energy storage due to their advantages of ultrahigh power density, flexibility, and scalability. To develop the polymer dielectric films with high-energy storage density has been a hot topic in the domain of dielectric energy storage. In this study, both of electric breakdown …
That is, compared with the methanol-based PVTC system, the methanebased PVTC system consumes less fossil energy to absorb the same amount of solar heat from the PV module. The integration of methane is therefore essential for both efficiency and fossil energy saving, which is enabled by the high operating temperature of PETE.
By storing solar energy as chemical energy, the PVTC-SOFC hybrid system realizes flexible storage and release of solar energy via dispatchable power generation through SOFC. Furthermore, the PVTC-SOFC hybrid system presents substantial advantages in mitigating CO 2 emissions owing to its efficient solar energy …
The PVTC system can achieve a theoretical net solar-electric efficiency (NSE) of up to 51.5% at an operating temperature of 498 K and high energy storage ratio [20]. As a key component of the PVTC system, the chemical reactor plays an important role in improving the net solar-electric efficiency and energy storage ratio of the system.
In particular, compared with the CCTO-PVTC composites, the energy storage properties of the $mathrm{CCTO} text{@} mathrm{SiO}_{2}-mathrm{PVTC}$ films are improved at given content. In addition, the thin SiO2 layer can not only improve the interfacial compatibility between CCTO and polymer matrix, but also delay the premature …
Conventional MSR reactors are challenged by undesirable performances in heat transfer and methanol conversion, impacting the performances of power generation and energy storage of PVTC systems. In this work, an innovative fractal tree-shaped structure is introduced into the flow channels configuration of an MSR reactor to enhance heat …
A new photovoltaic-thermochemical (PVTC) conceptual system integrating photon-enhanced thermionic emission (PETE) ... (NSE) efficiency of 39.1%; (2) high energy storage ratio, up to 80%; (3) high fossil energy saving and low CO 2 emission, with ~50% of 2 ...
2/PVTC nanocomposites possess a discharged energy storage density of 7.2 J/cm3 and an efficiency of 70.9% at an ultra-low content of ST@SiO 2 (1 vol%) and low electric field of 330 kV/mm. Meanwhile, the maxi-mum recoverable energy storage densities of ST NFs/PVTC (5.5 J/cm3) and pure PVTC (4.7 J/cm3) are inferior to that of ST@SiO 2/PVTC …
Generally, conversion to methanol and other value-added products is an effective strategy for CO 2 valorization. Some literature reports in the past have reviewed the CO 2 reduction with hydrogen over heterogeneous catalysts focusing on the different aspect of the field, including the CO 2 reduction to CO, methanol and hydrocarbons, their challenges and …
For example, in a PVTC system based on methanol decomposition, the net solar-to-electricity efficiency is up to 43%, which is 22% higher than that of a solar methanol decomposition system (35%), and the fossil …
Polymer film has a wide range of applications in power equipment because of its excellent energy storage characteristics. Here, an innovative approach of ferroelectric polymer composites with core-shell structured inorganic fillers is proposed. In this paper, the CaCu3Ti4O12(CCTO) nanoparticles are coated by SiO2 as inorganic …
A promising method in this direction is chemical energy storage, as the energy density of the chemical bond is unrivaled. At present, there are chiefly two alternatives under discussion: power-to-gas (PtG) producing methane (synthetic natural gas, SNG) and power-to-liquid, which stores electric power in the form of methanol.
Request PDF | On Jan 18, 2017, Chenzhen Liu and others published Challenges in various thermal energy storage ... our previous studies showed that a methanol-based PVTC system could reach a ...
The optimized energy storage density of 12.32 J/cm 3 and an efficiency of 64.87% are obtained in the SiO 2-2h/PVTC/BZT-1h/PVTC/SiO 2-2h multilayer composite films. The INL forms an interfacial barrier layer at …
methanol-based PVTC system could reach a theoretical net solar-to-electric efficiency of 43% [5], after major losses were taken into ... generation, energy storage and emission reduction could possibly be achieved in one system, taking advantage of the Fig. 2 ...
High penetration of photovoltaic (PV) power into the energy system could be challenged by its limited dispatchability related to fluctuations and intermittency of …
The maximal energy-storage density in the nanocomposite with 2.5 vol% BT NF-APS is about 5.6 J/cm3 at 3300 kV/cm, which is over 220% higher than that of the PVDF at the same electric field.
A hybrid solar energy conversion and storage system integrating a CdTe solar cell and methanol thermochemistry with a spectral filter assigning different parts of …
A general exploration of electric energy storage through hydrogen and methanol has been performed by Rihko-Struckmann et al. [6]. The authors conclude that while the methanol system yields a "poor" system energy efficiency of 17.6%, there are significant advantages of methanol over hydrogen due to practicality of methanol storage.